Background information on a radical science called nanotechnology.
KQED program: Introduction to Nanotechnology
www.youtube.com/watch?v=S4CjZ-OkGDs
Nanotechnology, defense-related areas of applications and research
Metastable intermolecular composites (MICs)Metastable intermolecular composites (MICs), also called
super-thermites or superthermites, are pyrotechnic compositions containing an oxidizer and a reducing agent which undergoes a very powerful exothermic reaction when heated to a critical temperature. They are variants of thermite compositions. MICs are a type of reactive materials investigated for military use.
What separates MICs from traditional thermites is that the oxidizer and a reducing agent, normally iron oxide and aluminum are not a fine powder, but rather nanoparticles. This dramatically increases the reactivity relative to micrometre-sized powder thermite. As the mass transport mechanisms that slow down the burning rates of traditional thermites are not so important at these scales, the reactions become kinetically controlled and much faster.
There are many possible thermodynamically stable fuel-oxidizer combinations. However, only a handful have been investigated. Some of them are:
* Aluminium-molybdenum(VI) oxide
* Aluminium-copper(II) oxide
* Aluminium-iron(III) oxide
* Antimony-potassium permanganate
* Aluminium-potassium permanganate
* Aluminium-bismuth(III) oxide
* Aluminium-tungsten(VI) oxide hydrate
* Aluminium-fluoropolymer (typically Viton)
* Titanium-boron (burns to titanium diboride)
Other compositions tested were based on nanosized RDX and with thermoplastic elastomers.
PTFE or other fluoropolymer can be used as a binder for the composition. Its reaction with the aluminium, similar to magnesium/teflon/viton thermite, adds energy to the reaction. <1>
Of the listed compositions, the Al-KMnO4 one shows the highest pressurization rates, followed by orders of magnitude slower Al-MoO3 and Al-CuO, followed by yet slower Al-Fe2O3. <2>
The nanoparticles can be prepared by spray drying from a solution, or in case of insoluble oxides, spray pyrolysis of solutions of suitable precursors. The composite materials can be prepared by sol-gel techniques or by conventional wet mixing and pressing.
The nanoscale composites are easier to ignite than traditional thermites. A nichrome bridgewire can be used in some cases. Other means of ignition can include flame or laser pulse.
MICs are investigated as possible replacement for lead (e.g. lead styphnate, lead azide) containing percussion caps and electric matches. Compositions based on Al-Bi2O3 tend to be used. PETN may be optionally added. <3><4>
MICs can be also added to high explosives to modify their properties. <5> Aluminium is typically added to explosives to increase their energy yield. Addition of small amount of MIC to aluminium powder increases overall combustion rate, acting as a burn rate modifier. <6>
Similar but not identical systems are nano-laminated pyrotechnic compositions. The fuel and oxidizer is not mixed as small particles, but deposited as alternating thin layers. <7>
External links
* Performance of Nanocomposite Energetic Materials Al-MoO3
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January 21, 2005, Technology Review
Military Reloads with Nanotech
Smaller. Cheaper. Nastier. Those are the guiding principles behind the military's latest bombs. The secret ingredient: nanotechnology that makes for a bigger boom.
By John Gartner
Nanotechnology is grabbing headlines for its potential in advancing the life sciences and computing research, but the Department of Defense (DoD) found another use: a new class of weaponry that uses energy-packed nanometals to create powerful, compact bombs.
With funding from the U.S. government, Sandia National Laboratories, the Los Alamos National Laboratory, and the Lawrence Livermore National Laboratory are researching how to manipulate the flow of energy within and between molecules, a field known as nanoenergentics, which enables building more lethal weapons such as "cave-buster bombs" that have several times the detonation force of conventional bombs such as the "daisy cutter" or MOAB (mother of all bombs).
Researchers can greatly increase the power of weapons by adding materials known as superthermites that combine nanometals such as nanoaluminum with metal oxides such as iron oxide, according to Steven Son, a project leader in the Explosives Science and Technology group at Los Alamos.
"The advantage (of using nanometals) is in how fast you can get their energy out," Son says.
Son says that the chemical reactions of superthermites are faster and therefore release greater amounts of energy more rapidly.
"Superthermites can increase the (chemical) reaction time by a thousand times," Son says, resulting in a very rapid reactive wave.
Son, who has been working on nanoenergetics for more than three years, says that scientists can engineer nanoaluminum powders with different particle sizes to vary the energy release rates. This enables the material to be used in many applications, including underwater explosive devices, primers for igniting firearms, and as fuel propellants for rockets.
However, researchers aren't permitted to discuss what practical military applications may come from this research.
Nanoaluminum is more chemically reactive because there are more atoms on the surface area than standard aluminum, according to Douglas Carpenter, the chief scientific officer at nanometals company Quantumsphere.
"Standard aluminum covers just one-tenth of one percent of the surface area (with atoms), versus fifty percent for nanoaluminum," Carpenter says.
Carpenter says the U.S. military has developed "cave-buster" bombs using nanoaluminum, and it is also working on missiles and torpedoes that move so quickly that they strike their targets before evasive actions can be taken.
"Nanoaluminum provides ultra high burn rates for propellants that are ten times higher than existing propellants," says Carpenter.... (more)
www.technologyreview.com/computing/14105/?a=f
link to www.cnanotech.com
Houston, Texas, January 24, 2002 -
Carbon Nanotechnologies, Inc. (CNI) said today that it has stepped up efforts to develop applications utilizing single-wall carbon nanotubes for defense and national security purposes. CNI has engaged the noted consulting firm of Technology Strategies & Alliances (TSA), headquartered in Burke, Virginia, near Washington, D. C., to assist in the strategic market development of national defense directed products. The company believes that an accelerated research effort will bring new and significantly improved products to market that can enhance national defense.
"The U.S. Department of Defense, the Navy, Air Force, Army, and NASA have been involved for some time in extensive research using single-wall carbon nanotubes or 'Buckytubes'," said Bob G. Gower, President of CNI. "We believe that Buckytubes can significantly enhance the ability of defense products to shield, absorb, or otherwise modify electro-magnetic signals, key needs in many mission-critical areas...
Center for NanoEnergetics Research
http://www.me.umn.edu/~mrz/CNER.htmCNER is an Army funded center created in the spring of 2001 and exists at four university sites, with the University of Minnesota as the lead institution.
http://www.me.umn.edu/~mrz/CNER.htmExternal Advisors-Collaborators
Dr. Alex Gash,Lawrence Livermore National Laboratory (LLNL)
Dr. Carl Melius,Lawrence Livermore National Laboratory (LLNL)
Dr. Andrzej Miziolek,Army Research Laboratory (ARL)
Dr. Betsy Rice,Army Research Laboratory (ARL)
Prof. Mintmire Oklahoma State University
link to www.cdc.gov
http://www.cdc.gov/niosh/topics/nanotech/nano_exchange_......Very little is known about the safety risks presented by engineered nanomaterials. From currently available information, the prevalent safety risks are most likely to involve catalytic effects or fire and explosion hazards....
"....Although insufficient information exists to predict the fire and explosion risk associated with nanoscale powders, nanoscale combustible material could present a higher risk than a similar quantity of coarser material...
...The greater activity of nanoscale materials forms a basis for research into nanoenergetics. For instance, nanoscale Al/MoO3 thermites ignite more than 300 times faster than corresponding micrometer-scale material...
link to www.bizjournals.com
November 25, 2005
A Texas company that has developed a powerful alternative to conventional lead-based munitions says it will commercialize and market its explosive compound through a spin-off company it plans to establish in New Mexico.
During a recent visit here, executives from Nanoenergetics Inc. said New Mexico's research and testing assets, economic incentives, growing private investment scene and accessible political leaders make it an ideal place to establish their new startup.
Nanoenergetics is being spun off from Austin-based Nanotechnologies Inc....
http://www.nanoscale.com/about.aspUnique nanoparticles, reactor technology and enabling applications
NANOTECHNOLOGIES, Inc. is a leading manufacturer of precision-engineered nanoparticles, with average particle sizes between 10 to 50 nanometers. Our expertise is in metal and metal oxide powders that are pure, discrete, spherical, and highly crystalline nanoparticles. NANOTECHNOLOGIES, Inc.'s materials allow customers to build new classes of products that we have labeled ANEASM, or "Advanced Nanoparticle Enabled ApplicationsSM".
NANOTECHNOLOGIES Inc. management team
http://www.nanoscale.com/about_team.aspDr. Dennis Wilson - Chief Technology Officer, Chairman of the Board and Founder
Dennis is co-founder of NANOTECHNOLOGIES, Inc. and co-inventor of the proprietary process. He received his Ph.D. in Mechanical Engineering from the University of Texas in 1977, and has more than 30 years of experience in industry, government, and university research. Dennis' expertise is in hypervelocity physics, plasma dynamics, aerothermodynamics, and materials synthesis...
...Dennis has eight years of technology management as founder and president of Applied Sciences, Inc. He has also served as director of special projects at the Institute for Advanced Technology. In addition, Dennis has been awarded a NASA Faculty Research Fellowship on three occasions, a DoE Research Fellowship twice, and an AFOSR Research Fellowship...
Darrin Willauer - Vice President, Engineering
Darrin joined NANOTECHNOLOGIES, Inc. in 2000 and is responsible for engineering development activities for all projects and research programs.
...project engineer with Dowell Schlumberger,
Dr. Kurt Schroder - Chief Scientist
Dr. Schroder joined NANOTECHNOLOGIES Inc. in 2000 and is a co-inventor of the core processes. He holds an S.B. in Physics from Massachusetts Institute of Technology and a Ph.D. in Physics from the University of Texas at Austin. He has over 15 years experience in plasma physics and pulsed power and has worked for industry, government, and academia. Kurt has numerous publications, 2 patents, and several patents pending in the following technology areas: vibration reduction and impact physics in hammers and sports rackets; blackbody radiation diagnostics and magnetic fluctuation measurements in tokamak plasmas; and onboard optical telemetry systems and launch package design and diagnostics on railguns.
link to www.cnanotech.com
Houston, Texas, January 24, 2002 -
Carbon Nanotechnologies, Inc. (CNI) said today that it has stepped up efforts to develop applications utilizing single-wall carbon nanotubes for defense and national security purposes. CNI has engaged the noted consulting firm of Technology Strategies & Alliances (TSA), headquartered in Burke, Virginia, near Washington, D. C., to assist in the strategic market development of national defense directed products. The company believes that an accelerated research effort will bring new and significantly improved products to market that can enhance national defense.
"The U.S. Department of Defense, the Navy, Air Force, Army, and NASA have been involved for some time in extensive research using single-wall carbon nanotubes or 'Buckytubes'," said Bob G. Gower, President of CNI. "We believe that Buckytubes can significantly enhance the ability of defense products to shield, absorb, or otherwise modify electro-magnetic signals, key needs in many mission-critical areas...