I must stress that I think "controlled demolition" is totally the wrong term to use when referring to the WTC event. However...
The guys from Controlled Demolition say it best themselves.
A two thousand ton skyscraper collapses like a house of cards, crumbling in on itself - a waterfall of well-fractured steel and concrete debris. It lasts only seconds, and buildings within a few meters stand untouched. The very essence of Controlled Demolition, Inc. is in our name: CONTROL.
http://www.controlled-demolition.com/Thermally stable explosives from Los Alamos Labs can handle temps over 480F. They don't say how much over, however.
"Our inorganic primaries, including the four new families, can be manufactured to be insensitive to light and moisture, sensitive to initiation but not too sensitive to handle and transport. They are thermally stable at more than 480˚F, chemically stable for extended periods, devoid of toxic metals such as lead, mercury, silver, barium, or antimony, and free of perchlorate," she said.
http://www.lanl.gov/news/index.php?fuseaction=home.story&story_id=8661Then there are thermally stable explosives that are only detonated by electrical pulse within a specific voltage range. These would be the ones I would use to get the job done. They offer the best chance of not being detonated accidentally.
An exploding foil initiator for operation with perforating gun assemblies or other equipment placed in a well borehole is set forth. This device utilizes a foil bridge adjacent to a flyer layer and a barrel having a central bore. When the foil bridge is vaporized, a disk is cut by the bore, and is directed through the bore of the barrel, traveling at a high velocity to deliver impact against a secondary explosive. The secondary explosive is formed of BRX explosive which is a pellet of explosive material of 1,3,5-trinitro-2,4,6-tripicrylbenzene. Detonation is accomplished with a high voltage, high current pulse of substantial voltage amplitude of about 1100 to not more than about 2000 volts.
http://www.freepatentsonline.com/5431104.html:shrug:
It could have been done, we have the technology. I still think "controlled demolition" is the wrong phrase, because it brings to mind the perfect felling of a tall building from the bottom, kink down the middle, right into its footprint. This was more "explosive demolition". It looked like they were blown up, rather than carefully crumpled. Don't know if this was helpful... I'm not an expert. I don't think we have any genuine demolitions experts here.
Edited to add:
Regarding the bit in the basement reported by Rodriguez, whom I personally have no reason to doubt is speaking the truth to what he experienced. I would absolutely want to blow out some of the bedrock embedded columns before blowing anything else. If you do not, when you blow the attached pieces higher in the building they will send tremors and you will get a lot of low level but still noticeable seismic activity. You definitely don't want that, it's just too much of a fingerprint.
They had to knock them out anyway, to get the building down. If I recall correctly, when the bombing happened in '93 they were amazed that it didn't do more damage, and the statement was made that the reason it didn't was because it was "only the basement", i.e., they didn't have any explosives on higher floors, thank god.
High rises, generally, are built so that if a fire happens on one floor it doesn't travel. If you've ever lived in one, you know this. The floors are concrete, concrete is just not very combustible. It holds it to the floor it started on. They have to do this, or high rises would just be too dangerous to live in. It takes a long time to walk down 20 flights of stairs, let alone 80. So the expectation of the fire moving through multiple floors, to floors unaffected by the crash, was likely not present.
I find it interesting that all the firefighters report that the windows on the ground floor (street level) of the North Tower were broken. They walked through the windows, didn't have to open the door. Yet, somehow, on the 84th floor, quite close to the plane impact floors, the windows were intact. The people up there had to break them to let air in the building, and let some smoke escape. This is very strange to my mind.