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The problem with most batteries is they take 4 watts of power to hold 1 watt of output. In small, low use power objects like cell phones and most electronics, this is a minor problem. In something like a car, it is the major problem.
Now most hybrids today, use a gasoline engine with Lead batteries. Lithium batteries can make the car lighter and thus more efficient, but even the Prius only goes about 20 minutes before the batteries have to be recharged (i.e. the engine turns on). The hybrids get their fuel efficiently from being able to use a significantly smaller and more efficient engine, that is gear to generate electrical power, with the batteries providing extra power as needed.
In conventional automobiles, the gasoline engine propels the car. At certain times the engine has to provide excessive power (i.e. pulling out onto a highway). At other times that same engine is just running at a very low power output (Cruising down the road for example). The Hybrid takes this excessive power of the gasoline or diesel engine to charge the batteries. The batteries are then used to propel the vehicle when the gasoline engine is off. When the Batteries need charged the Gasoline engine comes back on again. When extra power is needed the engine is used fully and extra power is provided by the batteries. Thus the Gasoline engine does NOT have to be the same power as in a conventional car and the Hybrid would have very similar performance to a conventional car, but with a significantly smaller engine. The Smaller engine is offset by the Batteries, but together the car weighs about the same as a conventional car, but both working together you get overall better fuel economy for the gasoline engine is NOT needed all the time, and when it is operating any excess power is being used to charge the batteries which takes over when the gasoline engine is not needed for electrical generation.
I go into the details, for it is the gasoline engine that is the key to the Hybrid, for it can be smaller and operates more often at full efficiency then in a Conventional car, with its waste of having a large engine stay on even if full power of that engine is not needed. The batteries and generators are just ways to make the Gasoline engine more efficient.
Thus converting lead acid batteries to lithium will help a little bit, but the weight difference is NOT that much, given that the sole purpose of the batteries is to provide about 30 minutes of drive time. After 30 minutes even the lithium batteries will need charged and will be charged by the Gasoline engine.
One of the problem is what if it was possible to use a engine to its full capacity without making the car a hybrid? That is possible, but it requires the car is sacrifice top end performance. This is what VW did with its Lupo, which was even better than the Prius when it came to fuel economy, but was NOT marketed in the US so VW could NOT make that claim in the US (Only EPA fuel numbers can be used in the US and the Lupo was NEVER even tested by the EPA for VW had no plans to market it in the US). The Lupo was a small car with an small engine, that operated when needed, but turned off when not even if the car was in motion. This system increased fuel economy even more than a Hybrid, but at the cost of decreased performance (i.e. no capably of 50 mph driving, the engine did NOT produce that much power).
When I did research on this issue a few years ago, the problem was NOT the batteries, but the whole concept that you had to have a car that can do 104 mph (Gore's son drove his car that fast last spring when he had a run in with the Police). A Lupo could NOT go that fast, but do you really need to go that fast? Do you really need to have the Capability to go that fast? I do not think so, but then I ride a 80cc Motor Scooter that gets 90mpg while I drive it on the local highways up to 45 mph (Through on the local mountains, I live in Appalachian Mountains of Pa, that top speed drops to 20 mph). It gets me where I am going, it uses its maximum power to get me there. The motor scooter is operating at maximum efficiency do to its small engine. The engine has no extra power, no matter how hard I try its will NOT go over 50 mph even down Chestnut Ridge.
Thus the problem with cars is NOT the efficiency of the batteries or the weight of the batteries, but the size of the Diesel or Gasoline engine it is combined with. The engine in the Prius is NOT the most efficient for it has to be able to go 104mph. That speed capability comes from a large engine and that means weight. My 80 cc Honda weighs 167 pounds, the Prius just under 3000 pounds. I get 90 (and that includes going up and down my local mountains), the EPA says the Prius gets 45 mph (Actual Mileage is generally less, but in the case of the Prius not as much as other cars the EPA test). Also note my 90mpg is my ACTUAL mileage NOT EPA (EPA does not test motor bikes for the simple reason the weight of the driver can vary the mileage, people who eight less than my 80cc gets over 100 mpg on it). The lithium battery will NOT help this situation. The weight saved will be under 100 pounds, the fuel economy increase will be minor.
When I did my research a few year back the small engine gasoline engine looked (and continues to look) like the better long term option. The decreased performance is more then compensated by the increase mileage and without the extra cost of having two engines, the Gasoline/Diesel and the Electric batteries. My 80 cc Motor Scooter cost me only $2000, the Prius is about 10 times that figure. Most people use their car primarily from home to work, thus the fact the Prius has seats for three that is rarely used a minor problem. That the Prius is a car and thus protects the driver from the weather is a plus on the side of a Hybrid, but I like driving my Motor Scooter even in winter, so a small plus at best.
My point is simple, there are ways to improve efficiency without going to hybrids, those require more sacrifices then most people want to do today, but are doable. The problem is that today Hybrids use their batteries in such a way that switching to Lithium will NOT improve fuel economy by that much, for the saving in weight is not that great given how Batteries are actually used in Hybrids. Converting to Lithium will provide some improvement, but no where near as much as a decision to cut down the size of the engine in today's cars.
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